Define electrode potential and standard electrode potential
Electrode Potential:
- The electrode potential, also known as the half-cell potential, is the electric potential of an electrode in an electrochemical cell relative to a standard reference electrode.
- The standard reference electrode is usually the hydrogen electrode, which has a defined potential of 0.00 volts.
- The electrode potential of an electrode is a measure of its tendency to participate in an oxidation-reduction reaction.
- An electrode with a positive potential is more likely to be oxidized, while an electrode with a negative potential is more likely to be reduced.
Standard Electrode Potential:
- The standard electrode potential is the potential of an electrode in an electrochemical cell relative to the standard hydrogen electrode (SHE) when both electrodes are in their standard states.
- The standard state of an electrode is defined as its potential in a solution of 1 M concentration at a pressure of 1 atm and a temperature of 25°C.
- The standard electrode potential of an electrode is a measure of the Gibbs free energy change of the redox reaction taking place at the electrode.
- A positive standard electrode potential indicates a spontaneous redox reaction, while a negative standard electrode potential indicates a non-spontaneous redox reaction.